Trichloroisocyanuric acid

Trichloroisocyanuric acid

IUPAC name 1,3,5-trichloro-1,3,5- triazinane-2,4,6-trione
Other names TCICA, 1,3,5-trichloro-1,3,5-triazine -2,4,6(1H,3H,5H)-trione, Symclosene, trichloro-s-triazinetrione, TCCCA, trichlor
Identifiers
CAS number	87-90-1^Y
PubChem	6909
ChemSpider	6643^Y
UNII	RL3HK1I66B^Y
ChEBI	CHEBI:33015^Y
RTECS number	XZ1925000
Jmol-3D images	Image 1
SMILES ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O
InChI InChI=1S/C3Cl3N3O3/c4-7-1(10)8(5)3(12)9(6)2(7)11^Y Key: YRIZYWQGELRKNT-UHFFFAOYSA-N^Y InChI=1/C3Cl3N3O3/c4-7-1(10)8(5)3(12)9(6)2(7)11 Key: YRIZYWQGELRKNT-UHFFFAOYAR
Properties
Molecular formula	C₃Cl₃N₃O₃
Molar mass	232.41 g/mol
Appearance	colourless solid
Density	2.19 ± 0.1 g/cm³
Melting point	246–47 °C
Boiling point	decomp.
Solubility in water	0.2%
Solubility in other solvents	chlorocarbons acetone acetonitrile
Structure
Coordination geometry	planar
Dipole moment	0 D
Hazards
R-phrases	R8, R22, R31, R36/37, R50/53
S-phrases	S8, S26, S41, S60, S61
Main hazards	lung irritant
Flash point	NA
Related compounds
Related compounds	Cyanuric chloride dichloroisocyanuric acid Tribromoisocyanuric acid
Y (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Trichloroisocyanuric acid is the organic compound with the formula (C₃Cl₃N₃O₃). It is used as an industrial disinfectant, bleaching agent and a reagent in organic synthesis.^[1]^[2] This white crystalline powder, which has a strong "chlorine odour," is sometimes sold in tablet or granule form for domestic and industrial use.

1 Use in water treatment
2 See also
3 References
4 External links

Use in water treatment

The compound is a disinfectant, algicide and bactericide mainly for swimming pools and dyestuffs, and is also used as a bleaching agent in the textile industries.

Applications: It is widely used in civil sanitation, pools and spas, preventing and curing diseases in husbandry and fisheries, fruits and vegetables preservation, wastewater treatment, algaecide for recycling water of industry and air conditioning, anti shrink treatment for woolen, treating seeds, bleaching fabrics, and organic synthesis industry

Benefits of TCCA in Swimming Pool-

Available with 90% chlorine concentration
Due to high chlorine content, handling is easy for large pools.
Reduces chlorine loss during day time. TCCA is stable it does not strip like any other halogen compounds.
Reduces algae growth.
Dissolves slowly in water, allowing for continuously metered dosing of available chlorine, especially when in tablet form.

Drawbacks of TCCA in Swimming Pool-

Cyanuric Acid (CYA) build-up from TCCA use can decrease the effectiveness of Free Active Chlorine (FAC) over time.
Such build up can only be reduced by dilution with water that does not contain CYA.
The economics of this effect can greatly reduce the cost-effectiveness of high chlorine availability in TCCA.
At high CYA concentrations, normal chlorine levels can be rendered ineffective, requiring either dilution by draining and refilling the pool or by adding abnormally high doses of chlorine to overcome this effect.

References

^ Hiegel, G. A. "Trichloroisocyanuric Acid" in Encyclopedia of Reagents for Organic Synthesis 2001, John Wiley & Sons: New York. DOI: 10.1002/047084289X.rt209
^ Barros, J. C. "Trichloroisocyanuric acid". Synlett 2005: 2115-2116. DOI: 10.1055/s-2005-872237 [1]

External links

Symclosene data page
Safety data for trichloroisocyanuric acid from Oxford University Chemistry Department.

Trichloroisocyanuric acid

Contents

Use in water treatment

See also

References

External links